What DVD is it?Try a different DVD title. I watch DVDs on my TV all the time using PowerDVD ver3 and my Matrox G450's tv-out .I don't think its a PowerDVD issue ?check all your vid card settings.I think sbcanada has a mx400 tv-out and I've seen some posts from him on being able to watch DVDs on his TV.
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Win98se/Mandrake 8.1
IwillKK266+
VolcanoII/RadioShack paste
1.2ghz 266DDR T-bird @ 1.4
384 MB PC133
16XDVD
6424CDRW
Matrox G450 32MB AGP
Viewsonic G90f 19"
Win 7
Asrock Z68 Extreme3 Gen3
I5 2500k @4ghz
8Gb DDR3 2133Mhz
Crucial M4 128Gb SataIII SSd
Sapphire Radeon 6870
Samsung 931bf 19" LCD
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